A COMPLEX WITH 3-COORDINATE TUNGSTEN ATOM - [(SILOX)2W=N-TERT-BU](SILOX=(TERT-BU)3SIO)

被引：40

作者：

EPPLEY, DF

WOLCZANSKI, PT

VANDUYNE, GD

机构：

[1] Cornell University, Department of Chemistry, Baker Laboratory I, Ithaca, New York

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 05期

关键词：

D O I：

10.1002/anie.199105841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Short W-N and W-O distances, as well as nearly linear W-N-C and W-O-Si units characterize the trigonal-planar, slightly distorted coordination sphere of the W atom in 1. Emerald-green crystals of 1 are formed in very high yield on reduction of the chloro complex 2 in diethyl ether. Compound 1 is stable as a solid, but decomposes in benzene with a half-life of 1 h.

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页码：584 / 585

页数：2

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