FROM FOURFOLD FUNCTIONALIZED CYCLOPHANES TO TUBE-SHAPED MOLECULES

被引：34

作者：

SCHRODER, A ^{[1
]}

KARBACH, D ^{[1
]}

GUTHER, R ^{[1
]}

VOGTLE, F ^{[1
]}

机构：

[1] UNIV BONN, INST ORGAN CHEM & BIOCHEM, GERHARD DOMAGK STR 1, W-5300 BONN 1, GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 08期

关键词：

HETERAPHANES; CYCLOPHANES; MACROCYCLES; TUBE-SHAPED MOLECULES; PHANES;

D O I：

10.1002/cber.19921250815

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of fourfold functionalized 2,11-dithia- and 2,11-diaza[3.3]cyclophanes 15 - 17 and 18 - 22, resp., is prepared by using a new multistep-strategy starting from 7 or m-xylene, respectively. The cyclophanes are used to construct tube-shaped molecules of type 24 by macrocyclization reactions of e. g. 21 and 22. Macrocycle 24 turns out to be conformationally flexible.

引用

页码：1881 / 1887

页数：7

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