STRUCTURE OF BIS(4-CHLOROPHENOLATO)[HYDROTRIS(3,5-DIMETHYL-1-PYRAZOLYL)BORATO]-OXOMOLYBDENUM(V)

被引：7

作者：

CHANG, CSJ ^{[1
]}

PECCI, TJ ^{[1
]}

CARDUCCI, MD ^{[1
]}

ENEMARK, JH ^{[1
]}

机构：

[1] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191012441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Mo(C15H22BN6)(C6H4ClO)2O], M(r) = 664.24, triclinic, P1BAR, a = 10.585 (2), b = 12.068 (3), c = 13.728 (3) angstrom, alpha = 88.01, beta = 69.94, gamma = 65.78-degrees, V = 1490.8 angstrom 3, Z = 2, D(x) = 1.48 g cm-3, Mo K-alpha, lambda = 0.71073 angstrom, mu = 6.5 cm-1, F(000) = 678, T = 296 (1) K, R = 0.034, wR = 0.049 for 4634 observed independent reflections with F2 > 3-sigma(F2). This is the second structurally characterized mononuclear monooxo transition-metal complex containing the phenolato ligand. The molecule exhibits a distorted octahedral coordination geometry, and the Mo atom is ligated by a terminal O atom, two p-chloro-substituted phenolato groups, and a tridentate facially coordinated hydrotris(3,5-dimethylpyrazolyl)borate ligand (L).

引用

页码：1096 / 1097

页数：2

共 7 条

[1] SPECTROSCOPIC AND ELECTROCHEMICAL STUDIES OF MONOMERIC OXOMOLYBDENUM(V) COMPLEXES WITH 5-MEMBERED CHELATE RINGS AND ALKOXO OR ALKANETHIOLATO LIGANDS [J].