A FACILE SYNTHESIS OF CYANOHYDRIN TRIMETHYLSILYL ETHERS BY THE ADDITION-REACTION OF TRIMETHYLSILYL CYANIDE WITH ALDEHYDES UNDER BASIC CONDITION

被引:175
作者
KOBAYASHI, S
TSUCHIYA, Y
MUKAIYAMA, T
机构
关键词
D O I
10.1246/cl.1991.537
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the presence of a catalytic amount of Lewis base such as amine, phosphine, arsine or antimony, trimethylsilyl cyanide (TMS-CN) smoothly reacts with aldehydes to afford the corresponding cyanohydrin trimethylsilyl ethers in excellent yields.
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页码:537 / 540
页数:4
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