COMPLEXATION OF CARBONYL-COMPOUNDS WITH AN ORGANIC SALT DOMINATED BY ACID-BASE INTERACTIONS IN DICHLOROMETHANE

被引：17

作者：

BELL, DA ^{[1
]}

ANSLYN, EV ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 03期

关键词：

D O I：

10.1021/jo00082a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Small neutral carbonyl compounds (2-5) form very stable complexes (K-a's ranging from 10(3) to 10(5) M(-1)) with ethyl 2,6-diaminonicotinium tetrakis(3,5-bis (trifluoromethyl)phenyl)borate (1) in dichloromethane. The dominant driving force for complexation is the strength of the acid-base interaction between the host and guest.

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页码：512 / 514

页数：3

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