PALLADIUM-CATALYZED VINYLATION OF TERTIARY ALLYLIC ALCOHOLS - A NEW PROTOCOL FOR THE SYNTHESIS OF ISOPRENOID ALDEHYDES

被引：24

作者：

BIENAYME, H

YEZEGUELIAN, C

机构：

[1] Rhône-Poulenc, Centre de Recherches des Carrières, 69192 Saint-Fons cedex

来源：

TETRAHEDRON | 1994年 / 50卷 / 11期

关键词：

PRENYLATION; ISOPRENOID ALDEHYDES; VITAMIN-A; RETINAL; HECK VINYLATION; PALLADIUM;

D O I：

10.1016/S0040-4020(01)87018-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Heck vinylation of tertiary allylic alcohols with iodo-acetal Ic, followed by an acid catalysed acetal hydrolysis-dehydration reaction, furnished isoprenoid aldehydes regioselectively in high yields

引用

页码：3389 / 3396

页数：8

共 67 条

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