ALLYLIC REARRANGEMENTS DURING THE RHODIUM-CATALYZED REACTIONS OF 2-ALLYLOXYBENZYLAMINES AND 2-(N-ALLYL-N-BENZYLAMINO)BENZYLAMINE

被引：26

作者：

CAMPI, EM ^{[1
]}

JACKSON, WR ^{[1
]}

MCCUBBIN, QJ ^{[1
]}

TRNACEK, AE ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 24期

关键词：

D O I：

10.1039/c39940002763

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of 2-allyloxybenzylamines with H-2/CO in the presence of rhodium catalysts give 1,3-benzoxazines via a reaction which involves allylic cleavage and carbonylation as demonstrated by crossover experiments.

引用

页码：2763 / 2763

页数：1

共 5 条

[1] DONOVAN RD, 1994, 208TH ACS NAT M WASH
[2] SYNTHESIS AND CHARACTERIZATION OF RHODIUM(I) AMINO OLEFIN COMPLEXES
KRAFFT, ME
WILSON, LJ
ONAN, KD
[J]. ORGANOMETALLICS, 1988, 7 (12) : 2528 - 2534
[3] MCDONAGH AF, 1968, J ORG CHEM, V33, P1, DOI 10.1021/jo01265a001
[4] EXAMPLE OF THERMODYNAMIC CONTROL IN PALLADIUM-CATALYZED ALLYLIC ALKYLATION - EVIDENCE FOR PALLADIUM-ASSISTED ALLYLIC C-C BOND-CLEAVAGE
NILSSON, YIM
ANDERSSON, PG
BACKVALL, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) : 6609 - 6613
[5] NUCLEOPHILIC-SUBSTITUTION AT THE CENTRAL ALLYL CARBON-ATOM OF A (PI-ALLYL)PLATINUM COMPLEX
OHE, K
MATSUDA, H
MORIMOTO, T
OGOSHI, S
CHATANI, N
MURAI, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) : 4125 - 4126

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