TRANSIENT STUDIES ON INTRAMICELLAR EXCIMER FORMATION - USEFUL PROBE OF THE HOST MICELLE

被引:172
作者
ATIK, SS
NAM, M
SINGER, LA
机构
[1] Department of Chemistry, University of Southern California, Los Angeles
关键词
D O I
10.1016/0009-2614(79)87109-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transient studies on the monomer-excimer reactions of pyrene and sodium 5-[1-pyrenyl]pentanoate in the cetyltrimethylammonium chloride (CTAC) and sodium dodecylsulfate (SDS) micelles lead to estimates of [MT] (total micelle concentration) and kE (rate constant for intramicellar excimer formation). Changes in [MT] and kE are observed with additives >1.0 × 10-3 M (sodium hexanoate in CTAC and n-dodecyl alcohol in SDS). © 1979.
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页码:75 / 80
页数:6
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