THERMOLYSIS OF THE PHENYLTIN CHLORIDES, PHXSNCL4-XI (X=1-3) - PRODUCTS AND PATHWAYS

被引：4

作者：

CHANDRASIRI, JA ^{[1
]}

WILKIE, CA ^{[1
]}

机构：

[1] MARQUETTE UNIV,DEPT CHEM,MILWAUKEE,WI 53233

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1993年 / 7卷 / 08期

关键词：

THERMOLYSIS; TRIPHENYLTIN CHLORIDE; DIPHENYLTIN DICHLORIDE; PHENYLTIN TRICHLORIDE; BIPHENYL; TERPHENYL; POLYPHENYL;

D O I：

10.1002/aoc.590070802

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The thermal degradation of triphenyltin chloride, diphenyltin dichloride and phenyltin trichloride has been studied by pyrolysis at 375-degrees-C in sealed tubes for various time periods. In all cases, biphenyl and tin(II) chloride are produced. For both phenyltin trichloride and diphenyltin dichloride, ter- and poly-phenyls are also obtained. In some cases tin(IV) chloride or elemental tin are obtained. Pathways that account for all observed products are presented.

引用

页码：599 / 605

页数：7

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