OLEANOLIC ACID SAPONINS FROM ROOT BARK OF ARALIA-ELATA

被引：47

作者：

SAKAI, S ^{[1
]}

KATSUMATA, M ^{[1
]}

SATOH, Y ^{[1
]}

NAGASAO, M ^{[1
]}

MIYAKOSHI, M ^{[1
]}

IDA, Y ^{[1
]}

SHOJI, J ^{[1
]}

机构：

[1] SHOWA UNIV,SCH PHARMACEUT SCI,SHINAGAWA KU,TOKYO 142,JAPAN

来源：

PHYTOCHEMISTRY | 1994年 / 35卷 / 05期

关键词：

ARALIA ELATA; ARALIACEAE; ROOT; OLEANOLIC ACID; BIS-GLYCOSIDE; GLUCURONIDE; SAPONIN; CHIKUSETSUSAPONIN; PSEUDOGINSENOSIDE RT(1); TARASAPONIN; ARALOSIDE;

D O I：

10.1016/S0031-9422(00)94846-5

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Three new oleanolic acid glycosides, tarasaponins I-III, were isolated as their methyl esters from the root bark of Aralia elata together with four known glycosides, the methyl esters of chikusetsusaponins IVa, IV, 28-desglucosyl-chikusetsusaponin IV and pseudoginsenoside RT(1). Tarasaponins I-III were characterized as oleanolic acid 3-0-[beta-D-glucopyranosyl(1-->3)][alpha-L-arabinofuranosyl(1-->4)]-beta-D-glucuronopyranoside, oleanolic acid 3-0-[beta-D-xylopyranosyl(1-->2)][beta-D-galactopyranosyl(1-->3)]-beta-D-glucuronopyranoside and beta-D-glucopyranosyl oleanolate 3-0-beta-D-galactopyranosyl(1-->3)-beta-D-glucuronopyranoside, respectively.

引用

页码：1319 / 1324

页数：6

共 14 条

[1]

KOCHETKOV N, 1961, ZH OBSHCH KHIM+, V31, P658

[2]

KOCHETKOV NK, 1962, TETRAHEDRON LETT, P713

[3]

KOCHETOKOV NK, 1961, CHEM ABSTR 22367C, V55

[4]

KOCHETOKOV NK, 1963, IAN SSSR KH, V1398, P1409

[5] STUDIES ON CONSTITUENTS OF PANACIS JAPONICI RHIZOMA .2. STRUCTURE OF CHIKUSETSUSAPONIN 4 AND SOME OBSERVATIONS ON STRUCTURAL RELATIONSHIP WITH ARALOSIDE A [J].

KONDO, N ;

SHOJI, J ;

NAGUMO, N ;

KOMATSU, N .

YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1969, 89 (06) :846-+

[6]

LIN TD, 1976, CHEM PHARM BULL, V24, P253

[7]

MORITA T, 1986, CHEM PHARM BULL, V34, P4833

[8]

OHWI J, 1972, FLORA JAPAN, P961

[9] RESOLUTION OF THE ENANTIOMERS OF ALDOSES BY LIQUID-CHROMATOGRAPHY OF DIASTEREOISOMERIC 1-(N-ACETYL-ALPHA-METHYLBENZYLAMINO)-1-DEOXYALDITOL ACETATES [J].

OSHIMA, R ;

YAMAUCHI, Y ;

KUMANOTANI, J .

CARBOHYDRATE RESEARCH, 1982, 107 (02) :169-176

[10] PLANT METABOLITES - TRITERPENOID SAPONINS FROM CALENDULA-ARVENSIS [J].

PIZZA, C ;

ZHOU, ZL ;

DETOMMASI, N .

JOURNAL OF NATURAL PRODUCTS, 1987, 50 (05) :927-931

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