RADIOLYTIC SYNTHESIS AND CHARACTERIZATION OF [RU-II(ACAC)(2)(CO)L] (L=MEOH, ETOH OR PR(I)OH)

被引：4

作者：

REMITA, H

BRIK, ME

DARAN, JC

DELCOURT, MO

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CHIM ORGAN STRUCT LAB,URA 1384,F-91405 ORSAY,FRANCE

[2] UNIV PARIS 06,CHIM MET TRANSIT LAB,URA 419,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 486卷 / 1-2期

关键词：

RUTHENIUM; RADIOLYSIS; ACETYLACETONATE; SYNTHESIS; X-RAY STRUCTURE;

D O I：

10.1016/0022-328X(94)05103-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The radiolysis of alcoholic solutions of [Ru-III(acac)(3)] under CO leads selectively to the formation of a new complex [Ru-II(acac)(2)(CO)L] (L = MeOH, EtOH or (PrOH)-O-i). [Ru-II(acac)(2)(CO)MeOH] 1 has been characterized by microanalysis, UV-visible, IR, C-13-NMR and H-1-NMR spectroscopies. The X-ray structural study of the complex 1 is also reported.

引用

页码：283 / 285

页数：3

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