SYNTHESIS OF SOLUBLE COBALTACYCLOPENTADIENE OLIGOMERS AND POLYMERS

被引：7

作者：

MATSUDA, N ^{[1
]}

SHIMURA, T ^{[1
]}

ARAMAKI, K ^{[1
]}

NISHIHARA, H ^{[1
]}

机构：

[1] JRDC,PRESTO,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

SYNTHETIC METALS | 1995年 / 69卷 / 1-3期

关键词：

Cobaltacyclopentadiene - Ethynylbenzene - Metallacycling polymerization - Stereoselectivity;

D O I：

10.1016/0379-6779(94)02568-J

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Soluble poly (cobaltacyclopentadienylene phenylene) was synthesized by the metallacycling polymerization method using (hexCp)Co(PPh(3))(2) (hexCp = n-hexylcyclopentadienyl) as the starting material. Wavelength of peak edge in its UV-VIS spectra increases with increasing the degree of polymerization, indicating an increase in the average pi-conjugation length.

引用

页码：559 / 560

页数：2