A spectroscopic study of the dynamical state of orientation of diatomic polar molecules in liquid non-polar solvents

被引：19

作者：

Robert, D. ^{[1
]}

Galatry, L. ^{[1
]}

机构：

[1] Fac Sci, Spect Hertzienne Lab, Grp Phys Mol, Besancon 25, France

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 1卷 / 11期

关键词：

D O I：

10.1016/0009-2614(68)80009-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A calculation of the absorption profile of a polar diatomic molecule dissolved in a non-polar solvent is presented. The agreement with experimental data suggests to consider that the dynamical state of orientation of a dissolved simple molecule in a liquid is not able to be represented by a perturbed rotation, nor by a libration. but is intermediate between these two limiting cases.

引用

页码：526 / 528

页数：3

共 6 条

[1] STATISTICAL PROPERTIES OF MOLECULAR INTERACTIONS IN LIQUID SOLUTIONS .1. GENER FORMULATION
BONAMY, L
ROBERT, D
GALATRY, L
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1967, 1 (01) : 91 - &
[2] SPECTRAL EVIDENCE FO ROTATION OF MOLECULES IN LIQUID PHASE
DATTA, P
BARROW, GM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (06) : 2137 - &
[3] GALATRY L, 1965, CR HEBD ACAD SCI, V260, P2159
[4] MARTEAU P, COMMUNICATION
[5] Calculation of infrared band shapes in liquid solutions of diatomic polar molecules in nonpolar solvents
Robert, D.
Galatry, L.
[J]. CHEMICAL PHYSICS LETTERS, 1967, 1 (09) : 399 - 403
[6] ROBERT D, 1967, COMMUNICATION

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