MONOLAYER PHASES OF THE FATTY-ACIDS AND THEIR ETHYL-ESTERS

被引：10

作者：

BIBO, AM

KNOBLER, CM

PETERSON, IR

机构：

[1] UNIV MAINZ,INST PHYS CHEM,JAKOB WELDER WEG 11,W-6500 MAINZ,GERMANY

[2] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 46卷

关键词：

D O I：

10.1002/masy.19910460109

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The miscibility correspondence between water-surface monolayer phases of the fatty acids and their ethyl esters was determined. Ester phases were found corresponding to all the known phases of the acids, and vice versa, in similar relative positions of the pi-T diagram. Evidence is presented for the existence of a ninth distinct miscibility category, represented by a phase in each of the pure materials, and a tenth found only in mixtures. We propose a tentative correspondence to bulk smectic miscibility categories.

引用

页码：55 / 64

页数：10

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