The vacuum ultraviolet spectra of three transition metal hexacarbonyls

被引：17

作者：

Iverson, A. ^{[1
]}

Russell, B. R.

机构：

[1] N Texas State Univ, Dept Chem, Denton, TX 76203 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 04期

关键词：

D O I：

10.1016/0009-2614(70)85082-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reported are the vapor phase spectra of Cr(CO)(6), Mo(CO)(6), W(CO)(6) at 300 degrees K in the vacuum ultraviolet region 2200 - 1250 angstrom. Several new transitions are seen with preliminary interpretations in terms of a simple bond-exciton model and compared with some recent photoionization studies.

引用

页码：307 / 311

页数：5

共 13 条

[1] ELECTRONIC STRUCTURES OF METAL HEXACARBONYLS
BEACH, NA
GRAY, HB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (21) : 5713 - &
[2] SOLVENT-EFFECT STUDIES ON THE INFRA-RED SPECTRA OF METAL CARBONYLS
BOR, G
[J]. SPECTROCHIMICA ACTA, 1962, 18 (06): : 817 - 822
[3] ASSIGNMENT OF ELECTRONIC TRANSITIONS IN FLUOROMETHANES - A BOND EXCITON INTERPRETATION
EDWARDS, L
RAYMONDA, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (22) : 5937 - &
[4] The photoelectron spectrum of vanadium exacarbonyl
Evans, S.
Green, J. C.
Orchard, A. F.
Saito, T.
Turner, D. W.
[J]. CHEMICAL PHYSICS LETTERS, 1969, 4 (06) : 361 - 362
[5] ELECTRONIC STRUCTURES OF OCTAHEDRAL METAL COMPLEXES .1. METAL HEXACARBONYLS AND HEXACYANIDES
GRAY, HB
BEACH, NA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (19) : 2922 - &
[6] HERZBERG G, 1939, MOL SPECTRA MOL STRU, V1, P36
[7] PHOTOIONIZATION STUDIES OF METAL CARBONYLS .I. IONIZATION POTENTIALS AND BONDING IN GROUP VI METAL HEXACARBONYLS AND IN MONONUCLEAR CARBONYLS AND NITROSYL CARBONYLS OF IRON, COBALT, AND NICKEL
LLOYD, DR
SCHLAG, EW
[J]. INORGANIC CHEMISTRY, 1969, 8 (12) : 2544 - &
[8] VACUUM-ULTRAVIOLET ABSORPTION CROSS SECTIONS OF CO, HC1, AND ICN BETWEEN 1050 AND 2100 A
MYER, JA
SAMSON, JAR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (01) : 266 - &
[9] PRICE WC, 1969, ROYAL SOC M PHOT SPE
[10] EXPERIMENTAL AND THEORETICAL STUDY OF SIGMA-BOND ELECTRONIC TRANSITIONS IN ALKANES
RAYMONDA, JW
SIMPSON, WT
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (02) : 430 - &

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