SELECTIVE CONJUGATE REDUCTION OF ALPHA,BETA-UNSATURATED ESTERS AND AMIDES VIA SMI2-PROMOTED ELECTRON-TRANSFER PROCESS

被引：50

作者：

INANAGA, J ^{[1
]}

SAKAI, S ^{[1
]}

HANDA, Y ^{[1
]}

YAMAGUCHI, M ^{[1
]}

YOKOYAMA, Y ^{[1
]}

机构：

[1] KYUSHU UNIV 33, DEPT CHEM, FUKUOKA 812, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 12期

关键词：

D O I：

10.1246/cl.1991.2117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alpha,-beta-Unsaturated esters and amides were rapidly and selectively reduced to the corresponding saturated ones under mild conditions without affecting coexisting isolated double or triple bonds by using the reduction system, SmI2-N,N-dimethylacetamide (DMA)-proton source.

引用

页码：2117 / 2118

页数：2

共 8 条

[1] DIVALENT LANTHANIDE DERIVATIVES IN ORGANIC-SYNTHESIS .1. MILD PREPARATION OF SMI2 AND YBI2 AND THEIR USE AS REDUCING OR COUPLING AGENTS [J].