VARIATION IN THE ELECTRON COUNT AND GROUND-STATE OF [MN12O12(O2CR)16(H2O)4] (R = ME OR PH) BY METAL SUBSTITUTION AND REDOX CHANGES - PREPARATION AND PROPERTIES OF [MN8FE4O12(O2CME)16(H2O)4].4H2O.2MECO2H AND [NPRN4] [MN12O12(O2CPH)16(H2O)4].H2O

被引：55

作者：

SCHAKE, AR

TSAI, HL

DEVRIES, N

WEBB, RJ

FOLTING, K

HENDRICKSON, DN

CHRISTOU, G

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM,LA JOLLA,CA 92093

[2] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

[3] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As a means of varying the electron count of complexes [Mn12O12(O2CR)16(H2O)4] (1; R = Me or Ph), the aggregates [Mn8Fe4O12(O2CMe)16(H2O)4] 2 and [NPr(n)4] [Mn12O12(O2CPh)16(H2O)4] 3 have been prepared; magnetochemical measurements confirm that the unusual properties of 1 can be significantly altered by 'conversion' to 2 and 3.

引用

页码：181 / 183

页数：3

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