Upon the Hydrogen-Bonding Ability of the H4 and H5 Protons of the Imidazolium Cation

被引:50
作者
Abdul-Sada, Ala'a K. [1 ]
Al-Juaid, Salih [1 ]
Greenway, Anthony M. [1 ]
Hitchcock, Peter B. [1 ]
Howells, Matthew J. [1 ]
Seddon, Kenneth R. [1 ]
Welton, Thomas [1 ]
机构
[1] Univ Sussex, Sch Chem & Mol Sci, Brighton BN1 9QJ, E Sussex, England
关键词
D O I
10.1007/BF01374488
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal and molecular structures of [Me(2)Etim]Cl, [Me(2)Etim](2)[CoCl4], and [Me(2)Etim](2)[NiCl4] ([Me(2)Etim](+) = 1,2-dimethyl-3-ethylimidazolium cation) all contain evidence that the H4 and H5 protons of the imidazolium cation enter into hydrogen bonds; the implications of this observation for the interactions in room-temperature chloroaluminate(III) ionic liquids are considered.
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页码:391 / 394
页数:4
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