STUDIES ON PORE SYSTEMS IN CATALYSTS .15. INFLUENCE OF GEOMETRICAL FACTOR ON T CURVE MEASURED ON AEROSIL

被引：12

作者：

DEBOER, JH

LINSEN, BG

BROEKHOF.JC

OSINGA, TJ

机构：

[1] Department of Chemical Technology, Technological University of Delft

来源：

JOURNAL OF CATALYSIS | 1968年 / 11卷 / 01期

关键词：

D O I：

10.1016/0021-9517(68)90008-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In a previous article of this series it was shown that the t curve measured on Aerosil greatly deviates from the common t curve. In this article we shall treat this phenomenon in more detail. From the nitrogen-sorption isotherms, measured on four different aerosils, the t curves are calculated. It is shown that the magnitude of the deviations from the common t curve depends on the particle size of Aerosil. By calculations, based on geometrical and thermodynamic considerations, theoretical t values are obtained in perfect agreement with the experimental ones. © 1968.

引用

页码：46 / &

共 12 条

[1] STUDIES ON PORE SYSTEMS IN CATALYSTS .11. PORE DISTRIBUTION CALCULATIONS FROM ADSORPTION BRANCH OF A NITROGEN ADSORPTION ISOTHERM IN CASE OF INK-BOTTLE TYPE PORES [J].