5-HEXENYL CYCLIZATION

被引：52

作者：

SCHMID, P

GRILLER, D

INGOLD, KU

机构：

[1] Division of Chemistry, National Research Council of Canada, Ottawa, Ontario

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1979年 / 11卷 / 03期

关键词：

D O I：

10.1002/kin.550110309

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cyclization of the 5‐hexenyl radical to form the cyclopentylmethyl radical has been reexamined by kinetic EPR spectroscopy at temperatures between 183 and 232°K in cyclopropane solvent. The rate constant, kc for this important radical rearrangement can be represented by (Formula Presented.) where Θ = 2.3RT kcal/mol. Copyright © 1979 John Wiley & Sons, Inc.

引用

收藏

页码：333 / 338

页数：6

相关论文

共 35 条

[11] REACTIONS OF ALKALI BENZOPHENONE KETYLS WITH ALKYL IODIDES [J].

GARST, JF ;

SMITH, CD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (06) :1520-1526

[12] RATE CONSTANTS FOR BIMOLECULAR SELF-REACTIONS OF ETHYL, ISOPROPYL, AND TERT BUTYL RADICALS IN SOLUTIONS - DIRECT COMPARISON [J].

GRILLER, D ;

INGOLD, KU .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1974, 6 (03) :453-456

[13] RATES OF TERMINATION OF RADICALS IN SOLUTION .7. ALLYLIC RADICALS [J].

HEFTER, HJ ;

WU, CHS ;

HAMMOND, GS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (03) :851-855

[14]

INGOLD KU, 1973, FREE RADICALS, V1, pCH2

[15] STEREOCHEMISTRY AND MECHANISM OF PHOTOCHEMICAL AND THERMAL INSERTION OF OXYGEN INTO CARBON-COBALT BOND OF ALKYL(PYRIDINE)COBALOXIMES [J].

JENSEN, FR ;

KISKIS, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (20) :5825-5831

[16] FREE-RADICAL CYCLIZATIONS .17. MECHANISTIC STUDIES [J].

JULIA, M .

PURE AND APPLIED CHEMISTRY, 1974, 40 (04) :553-567

[17] FREE-RADICAL CYCLIZATIONS [J].

JULIA, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1971, 4 (11) :386-&

[18] ELECTRON SPIN RESONANCE OF PRIMARY ALKYL RADICALS . PHOTOLYSIS OF ACYL PEROXIDES [J].

KOCHI, JK ;

KRUSIC, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (14) :3940-&

[19]

KOSSA WC, 1971, TETRAHEDRON LETT, P3455

[20] KINETIC APPLICATIONS OF ELECTRON-PARAMAGNETIC RESONANCE SPECTROSCOPY .16. CYCLIZATION OF 5-HEXENYL RADICAL [J].

LAL, D ;

GRILLER, D ;

HUSBAND, S ;

INGOLD, KU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (20) :6355-6357

← 1 2 3 4 →