COMPOSITION AND GROWTH OF ANODIC OXIDE-FILMS ON IRON

被引：23

作者：

GRAHAM, MJ

BARDWELL, JA

GOETZ, R

MITCHELL, DF

MACDOUGALL, B

机构：

[1] Division of Chemistry, National Research Council of Canada, Ottawa

来源：

CORROSION SCIENCE | 1990年 / 31卷

关键词：

!sup]18[!/sup]O/SIMS; Anodic films; iron; Mössbauer; oxide breakdown; oxide growth; XPS;

D O I：

10.1016/0010-938X(90)90101-A

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

This paper will emphasize the use of surface-analytical techniques to study the nature of passive oxide films on Fe. 18O/SIMS has been used to determine the air stability, cathodic removal, growth and breakdown of anodic films formed in borate buffer solution. SIMS has also shown that these passive films contain no incorporated hydroxyl ions, and electron back-scattering Mössbauer spectroscopy (complemented by XPS) has confirmed that the films resemble small particle size crystalline γ-Fe2O3. Results will also be presented on the anodic passivation of Fe in sulfate and perchlorate solutions and on the influence of halide ions on passivation in borate buffer. © 1990.

引用

页码：139 / 148

页数：10

共 18 条

[1] USE OF O-18 SIMS AND ELECTROCHEMICAL TECHNIQUES TO STUDY THE REDUCTION AND BREAKDOWN OF PASSIVE OXIDE-FILMS ON IRON
BARDWELL, JA
MACDOUGALL, B
GRAHAM, MJ
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (02) : 413 - 418
[2] USE OF SIMS TO INVESTIGATE THE INDUCTION STAGE IN THE PITTING OF IRON
BARDWELL, JA
MACDOUGALL, B
SPROULE, GI
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (05) : 1331 - 1336
[3] BRETT ME, 1986, J ELECTROCHEM SOC, V133, P2032
[4] COMPOSITION OF ANODICALLY FORMED IRON-OXIDE FILMS
COHEN, M
MITCHELL, D
HASHIMOTO, K
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (03) : 442 - 444
[5] INSITU MOSSBAUER STUDIES OF PASSIVE FILMS ON IRON
ELDRIDGE, J
KORDESCH, ME
HOFFMAN, RW
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1982, 20 (04): : 934 - 938
[6] A MOSSBAUER-SPECTROSCOPY STUDY OF THE POTENTIAL DEPENDENCE OF PASSIVATED IRON FILMS
ELDRIDGE, J
HOFFMAN, RW
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (04) : 955 - 961
[7] PASSIVATION OF IRON IN BORATE BUFFER SOLUTION
FRANKENTHAL, RP
[J]. ELECTROCHIMICA ACTA, 1971, 16 (11) : 1845 - +
[8] STABILITY AND GROWTH OF PASSIVE FILMS ON PURE IRON IN BORATE BUFFER AS INVESTIGATED BY O-18-SIMS
GOETZ, R
MITCHELL, DF
MACDOUGALL, B
GRAHAM, MJ
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (03) : 535 - 539
[9] AN AES AND SIMS STUDY OF THE INFLUENCE OF CHLORIDE ON THE PASSIVE OXIDE FILM ON IRON
GOETZ, R
MACDOUGALL, B
GRAHAM, MJ
[J]. ELECTROCHIMICA ACTA, 1986, 31 (10) : 1299 - 1303
[10] ELLIPSOMETRIC-POTENTIOSTATIC STUDIES OF IRON PASSIVITY .I. ANODIC FILM GROWTH IN SLIGHTLY BASIC SOLUTIONS
KRUGER, J
CALVERT, JP
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1967, 114 (01) : 43 - &

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