SYNTHESIS OF PROPYLENE-OXIDE FROM PROPYLENE CHLOROHYDRINS .1. KINETIC ASPECTS OF THE PROCESS

被引：22

作者：

CARRA, S

SANTACESARIA, E

MORBIDELLI, M

CAVALLI, L

机构：

[1] SOCIETA EUTECO,MILANO,ITALY

[2] CTR NAZL TECNOL PROPULSIONE & ENERGETICA,MILANO,ITALY

来源：

CHEMICAL ENGINEERING SCIENCE | 1979年 / 34卷 / 09期

关键词：

D O I：

10.1016/0009-2509(79)85018-6

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The reactions involved in the industrial production of propylene oxide from chlorohydrins have been kinetically investigated. The kinetics of dehydrochlorination of propylene chlorohydrins have been studied, both in the presence of slaked lime and of caustic soda, by potentiometric techniques. The kinetic parameters of the reactions have been determined. The propylene oxide hydrolysis has been studied by measuring the decrease of the reagent during the time using NMR analysis. © 1979.

引用

页码：1123 / 1132

页数：10