INTERNAL REORIENTATIONS IN K2REH9 VIA WIDE-LINE AND PULSED PROTON RESONANCE STUDIES

被引：6

作者：

FARRAR, TC

TSANG, T

JOHANNESEN, RB

机构：

[1] Institute for Materials Research, National Bureau of Standards, Washington

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 08期

关键词：

D O I：

10.1063/1.1672554

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Proton spin-lattice relaxation times (T1) and second moments (M2) have been measured as a function of temperature for K2ReHg. The activation energies for internal reorientation of ReHg ions, and their rms errors, are 9.9±0.4 and 25.0±0.8 kj/mole (2.4±0.1 and 6.0±0.2 kcal/mole), respectively, for type a and d sites. Our results suggest that the barriers are determined by nearest-neighbor ReH 9--ReHag- interactions.

引用

页码：3595 / +

页数：1

共 19 条

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