CRYSTAL STRUCTURE OF AG2TEO2(OH)4

被引:12
作者
FISCHER, R
机构
[1] Institut für Mineralogie und Kristallographie der Universität Wien, Wien
来源
MONATSHEFTE FUR CHEMIE | 1969年 / 100卷 / 06期
关键词
D O I
10.1007/BF01151728
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of Ag2TeO2(OH)4 has been determined by single crystal X-ray methods and refined by the least squares method. The lattice parameters of the cell (Fdd 2-C2v19) are:a=18.72;b=6.48;c=8.94 Å. With all observed reflections an R-Value of 8.50% was obtained; if all Hamilton-reflections are included R=9.41%. The Te atoms are surrounded octahedrally by 6 oxygens, the 4 oxygens around the silver atoms form a distorted tetrahedron. Two of these tetrahedra" form with an intermediate octahedron a geometric unit. These units are linked together to a three-dimensional structure by oxygens belonging to two different "tetrahedra" and by hydrogen bondings. © 1969 Springer-Verlag."
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页码:1809 / &
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