THEORETICAL-STUDY OF PREDISSOCIATION IN DIATOMICS - CASE OF THE O2 B' 3-SIGMA-U- STATE

被引：9

作者：

CIMIRAGLIA, R ^{[1
]}

PERSICO, M ^{[1
]}

TOMASI, J ^{[1
]}

机构：

[1] CNR,CHIM QUANTIST & ENERGETICA MOLEC LAB,I-56100 PISA,ITALY

来源：

CHEMICAL PHYSICS | 1979年 / 42卷 / 03期

关键词：

D O I：

10.1016/0301-0104(79)80077-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The predissociation of excited O2 has been studied theoretically with the aid of a simple model describing the Rydberg-valence crossing which occurs in the B and B' 3Σ-u states. Calculations of the decay rates have been performed by means of a method described previously. The energy shifts caused by the interaction of a discrete state with the dissociative continuum have been computed by the Fano method. Isotopic effects and the dependence of decay rates and energy shifts on the minimum energy gap between the adiabatic curves have been emphasized. © 1979.

引用

页码：297 / 303

页数：7

共 19 条

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