ADSORPTION HYSTERESIS, CAPILLARY CONDENSATION, AND MELTING IN MULTILAYER METHANE FILMS ON GRAPHITE FOAM

被引:19
作者
LYSEK, MJ [1 ]
LAMADRID, M [1 ]
DAY, P [1 ]
GOODSTEIN, D [1 ]
机构
[1] CALTECH,CONDENSED MATTER PHYS 114-36,PASADENA,CA 91125
关键词
D O I
10.1021/la00039a026
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have studied adsorption hysteresis in the system multilayer methane adsorbed on graphite foam by measuring heat capacities on each branch of the hysteresis curve. We are able to show that, on the stable branch, capillary condensation begins, surprisingly, at 1.1 layers. These observations call into question previous conclusions about this and other multilayer adsorbed systems.
引用
收藏
页码:898 / 900
页数:3
相关论文
共 29 条
[1]   PHASE TRANSFORMATIONS OF WATER IN POROUS GLASS [J].
ANTONIOU, AA .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (10) :2754-&
[2]   SUPERCOOLED LIQUIDS AND SOLIDS IN POROUS-GLASS [J].
AWSCHALOM, DD ;
WARNOCK, J .
PHYSICAL REVIEW B, 1987, 35 (13) :6779-6785
[3]   HIGH PRECISION SCANNING RATIO CALORIMETER FOR USE NEAR PHASE-TRANSITIONS [J].
BUCKINGHAM, MJ ;
EDWARDS, C ;
LIPA, JA .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1973, 44 (09) :1167-1172
[4]  
Everett D.H., 1958, STRUCTURE PROPERTIES
[5]   A THERMODYNAMIC STUDY OF THE ADSORPTION OF BENZENE VAPOUR BY ACTIVE CHARCOALS [J].
EVERETT, DH ;
WHITTON, WI .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1955, 230 (1180) :91-110
[6]  
EVERETT DH, 1967, GAS SOLID INTERFACE, pCH36
[7]   SORPTION HYSTERESIS .2. THE ROLE OF THE CYLINDRICAL MENISCUS EFFECT [J].
FOSTER, AG .
JOURNAL OF THE CHEMICAL SOCIETY, 1952, (MAY) :1806-1812
[8]   PHASE-DIAGRAMS OF MULTILAYER ADSORBED METHANE [J].
GOODSTEIN, DL ;
HAMILTON, JJ ;
LYSEK, MJ ;
VIDALI, G .
SURFACE SCIENCE, 1984, 148 (01) :187-199
[9]  
GREGG SJ, 1967, ADSORPTION SURFACE A
[10]   THERMODYNAMIC STUDY OF METHANE MULTILAYERS ADSORBED ON GRAPHITE [J].
HAMILTON, JJ ;
GOODSTEIN, DL .
PHYSICAL REVIEW B, 1983, 28 (07) :3838-3848