OCCURRENCE OF LIGAND COUPLING IN THE REACTION OF THE 2-THIENYL SULFOXIDES WITH ORGANOMETALLIC COMPOUNDS

被引：11

作者：

OAE, S ^{[1
]}

INUBUSHI, Y ^{[1
]}

YOSHIHARA, M ^{[1
]}

机构：

[1] KINKI UNIV,DEPT APPL CHEM,OSAKA,OSAKA 577,JAPAN

来源：

HETEROATOM CHEMISTRY | 1993年 / 4卷 / 2-3期

关键词：

D O I：

10.1002/hc.520040211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of 2-pyridyl 2-thienyl sulfoxide with 2-thienyllithium was found to give both 2-(2-pyridyl)thiophene 2 and 2,5-(di-2-pyridyl)thiophene 3. The reaction between 2-thienyllithium and thionyl chloride was found to give 2,2'-bithienyl 8, a coupling product, which is also formed by the reaction between di-2-thienyl sulfoxide 7 and 2-thienyllithium.

引用

收藏

页码：185 / 188

页数：4

相关论文

共 23 条

[1]

FURUKAWA N, 1988, TETRAHEDRON LETT, V29, P5845

[2]

GRONOWITZ S, 1974, ACTA CHEM SCAND B, V208, P309

[3] QUANTITATIVE DETERMINATION OF THIOPHENOL, DIPHENYL DISULFIDE, AND PHENYL THIOLACETATE [J].

HARNISH, DP ;

TARBELL, DS .

ANALYTICAL CHEMISTRY, 1949, 21 (08) :968-969

[4] SCHWEFEL IN AROMATISCHEN VERBINDUNGEN ALS LIGANDTOM IN CHELATKOMPLEXEN [J].

KAHMANN, K ;

SIGEL, H ;

ERLENMEYER, H .

HELVETICA CHIMICA ACTA, 1964, 47 (07) :1754-+

[5] OCCURRENCE OF LIGAND COUPLING IN THE REACTIONS OF VARIOUS SULFOXIDES WITH GRIGNARD-REAGENTS [J].

KAWAI, T ;

KODERA, Y ;

FURUKAWA, N ;

OAE, S ;

ISHIDA, M ;

TAKEDA, T ;

WAKABAYASHI, S .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1987, 34 (3-4) :139-148

[6] A CONVENIENT PREPARATION OF BIPYRIDINES THROUGH LIGAND COUPLING REACTION WITH SIGMA-SULFURANE FORMED BY TREATMENT OF METHYL 2-PYRIDYL SULFOXIDE WITH GRIGNARD-REAGENTS [J].

KAWAI, T ;

FURUKAWA, N ;

OAE, S .

TETRAHEDRON LETTERS, 1984, 25 (24) :2549-2552

[7]

KAWAI T, 1985, THESIS U TSUBUKA TSU

[8] LIGAND-EXCHANGE AND LIGAND COUPLING VIA THE SIGMA-SULFURANE INTERMEDIATE IN THE REACTION OF ALKYL 2-PYRIDYL SULFOXIDE WITH GRIGNARD-REAGENTS - CONVENIENT PREPARATION OF 2,2'-BIPYRIDINES [J].

OAE, S ;

KAWAI, T ;

FURUKAWA, N .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1987, 34 (3-4) :123-132

[9] LIGAND COUPLING THROUGH HYPERVALENT INTERMEDIATES - REACTION OF HETEROARYL SULFOXIDES WITH ORGANOMETALLICS REAGENTS AND THEIR IMPLICATIONS [J].

OAE, S .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1986, 27 (1-2) :13-29

[10] LIGAND COUPLING THROUGH SIGMA-SULFURANE - COMPLETE RETENTION OF GEOMETRIC CONFIGURATION OF ALLYLIC AND VINYLIC GROUPS IN THE REACTIONS OF ALLYLIC AND VINYLIC SULFOXIDES WITH GRIGNARD-REAGENTS [J].

OAE, S ;

TAKEDA, T ;

WAKABAYASHI, S .

TETRAHEDRON LETTERS, 1988, 29 (35) :4445-4448