THERMODYNAMIC AND KINETIC-STUDIES ON REVERSIBLE LIQUID-PHASE DIELS-ALDER REACTION BETWEEN MALEIC-ANHYDRIDE AND 2-METHYL FURAN - DYNAMIC MODELING BY THERMAL-ANALYSIS

被引：3

作者：

BALBI, N

KHOUMERI, B

机构：

[1] Centre de Mathématiques et de Calcul Scientifique, Faculté des Sciences et des Techniques-Campus Grossetti, Université de Corse, Corse, 20250

来源：

JOURNAL OF THERMAL ANALYSIS | 1994年 / 42卷 / 2-3期

关键词：

DIELS ALDER REACTION; KINETIC STUDIES; THERMODYNAMIC STUDIES;

D O I：

10.1007/BF02548528

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The liquid phase reaction between maleic anhydride and 1-methyl-furan leads to an exothermic cycloaddition. The reaction enthalpy, the rate constant and the equilibrium constant are evaluated with good precision by a method of analysis using thermal data and a dynamic model based on physical properties. The mathematical models that are presented here in a simple way (first-order system) represent the reaction accurately and are useful for studying other reactions and even industrial processes.

引用

页码：461 / 466

页数：6

共 15 条

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