QUINONE DEHYDROGENATION .3. OXIDATION OF 2,4-DI-T-BUTYLPHENOL

被引：36

作者：

BECKER, HD

机构：

[1] General Electric Research, Development Center, Schenectady

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 05期

关键词：

D O I：

10.1021/jo01257a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of 2,4-di-t-butylphenol with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) in methanol leads to 2-methoxy-4,6,8-tri-t-butyldibenzofuran and a tetra-t-butyl-substituted benzofuranoxepinone. A sequence of one-electron and two-electron transfers to DDQ is proposed for this unusual dehydrogenation reaction. The preparation and isolation of a stable benzofuranoxepinoxy radical is described. © 1969, American Chemical Society. All rights reserved.

引用

页码：1198 / &

共 9 条

[1] QUINONE DEHYDROGENATION .2. OXIDATIVE DIMERIZATION OF ENOLS AND ENOLIZABLE KETONES [J].