MONOLAYERS AND PLANAR OR CURVED BILAYERS

被引:16
作者
GABRIELLI, G
机构
[1] Department of Chemistry, University of Florence
关键词
D O I
10.1016/0001-8686(91)80046-M
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Monolayers and planar or curved bilayers can be considered useful models of biologic membranes. With this in perspective we report on studies performed on monolayers and bilayers of polypeptides and lipids. The results obtained show that the study of monolayers allows either the deduction of the interphasal orientation in a one-component system or the reasons of mutual solubility when mixtures are considered. In the case of bilayers and particularly of BLM, LB films and vesicles, it is possible to gain information about stability and thickness of single component bilayers as well as about the influence of the addition of a second component on these properties. The comparison between the various systems taken into consideration allows us to draw a first conclusion: the condition to form BLM and vesicles is to start from monolayers in expanded phases while the condition to form plurilayers and LB films is to start from monolayers in condensed phases.
引用
收藏
页码:31 / 72
页数:42
相关论文
共 79 条
[1]  
ADAMSON AW, 1976, PHYSICAL CHEM SURFAC
[2]   2-COMPONENT MONOLAYERS .4. EXCESS ENTHALPIES AND ENTROPIES OF MIXING IN OCTADECANOL-DOCOSYL SULFATE SYSTEM [J].
BACON, KJ ;
BARNES, GT .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1978, 67 (01) :70-77
[3]   INTERACTION BETWEEN ALPHA-POLY(GAMMA-METHYL-L-GLUTAMATE) AND 5-DOXYLSTEARIC AND 16-DOXYLSTEARIC ACIDS - A MONOLAYER AND ELECTRON-SPIN-RESONANCE STUDY [J].
BAGLIONI, P ;
CARLA, M ;
DEI, L ;
MARTINI, E .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (06) :1460-1465
[4]   MONOLAYERS OF CHOLESTEROL AT WATER AIR INTERFACE - MECHANISM OF COLLAPSE [J].
BAGLIONI, P ;
CESTELLI, G ;
DEI, L ;
GABRIELLI, G .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1985, 104 (01) :143-150
[5]   MACROMOLECULAR CONFORMATIONS AT THE WATER-AIR INTERFACE - INTERACTIONS BETWEEN ALPHA-CONFORMATION AND BETA-CONFORMATION OF POLYPEPTIDES [J].
BAGLIONI, P ;
DEI, L ;
GABRIELLI, G ;
INNOCENTI, FM ;
NICCOLAI, A .
COLLOID AND POLYMER SCIENCE, 1988, 266 (09) :783-792
[6]   BIDIMENSIONAL STATE CONFORMATION OF POLY-GAMMA-METHYL-L-GLUTAMATE .1. ALPHA,BETA-CONFORMATIONS AND THEIR MIXTURES WITH ARACHIDIC ACID [J].
BAGLIONI, P ;
GALLORI, E ;
GABRIELLI, G ;
FERRONI, E .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1982, 88 (01) :221-232
[7]   BIDIMENSIONAL STATE CONFORMATION OF POLY-GAMMA-METHYL-L-GLUTAMATE .2. COLLAPSE MECHANISM OF ALPHA-CONFORMATION AND BETA-CONFORMATION [J].
BAGLIONI, P ;
DEI, L ;
GABRIELLI, G .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 93 (02) :402-410
[8]   ON THE MECHANISM OF COLLAPSE OF MONOLAYERS OF MACROMOLECULAR SUBSTANCES .2. CELLULOSE-ACETATE [J].
BAGLIONI, P ;
GABRIELLI, G ;
GUARINI, GGT .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1980, 78 (02) :347-355
[9]  
Birdi KS, 1989, LIPID BIOPOLYMER MON
[10]  
BLODGETT KB, 1944, PHYS REV, V51, P488