CHEMOSELECTIVE ALKYLATION OF THIOLS - A DETAILED INVESTIGATION OF REACTIONS OF THIOLS WITH HALIDES

被引：46

作者：

KHURANA, JM

SAHOO, PK

机构：

[1] Department of Chemistry, University of Delhi

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 12期

关键词：

D O I：

10.1080/00397919208020489

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Arylthiols, aralkylthiols and alkane thiols can be readily alkylated by alkyl/aralkyl halides in presence of K2CO3/DMF to yield unsymmetrical sulphides in nearly quantitative yields. 2-Mercaptoethanol gave the thioether chemoselectively.

引用

页码：1691 / 1702

页数：12

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