1,4-DIOXENE IN ORGANIC-SYNTHESIS - GENERATION AND REACTIVITY OF EPOXYDIOXENES

被引：16

作者：

BAYLON, C ^{[1
]}

HANNA, I ^{[1
]}

机构：

[1] ECOLE POLYTECH,CNRS,SYNTH ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 36期

关键词：

D O I：

10.1016/0040-4039(95)01307-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of various alkyldioxens with dimethyldioxirane is described. While pure epoxides were isolated from 4-dioxenylcyclohexanone 10 and diether 9, vinyldioxenes 11-14 gave the corresponding epoxide rearrangement products, alpha-ketal aldehydes 20-24, in excellent yields.

引用

页码：6475 / 6478

页数：4

共 18 条

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