NEW OXIDIZING-AGENTS FROM THE DEHYDRATION OF HYDROGEN-PEROXIDE

被引：50

作者：

REBEK, J ^{[1
]}

MCCREADY, R ^{[1
]}

WOLF, S ^{[1
]}

MOSSMAN, A ^{[1
]}

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM,LOS ANGELES,CA 90024

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 09期

关键词：

D O I：

10.1021/jo01323a026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The action of diverse dehydrating agents (activated ureas, isocyanates, cyanates, carbodiimides, and ortho esters) on anhydrous hydrogen peroxide is shown to generate intermediates which are effective epoxidizing agents for olefins. These reagents react rapidly with olefins, operate under mild conditions, and produce neutral byproducts. The applicability of these reagents to synthesis is explored. In the absence of olefins the dehydrating agents react with H2O2 to produce singlet molecular oxygen. © 1979, American Chemical Society. All rights reserved.

引用

页码：1485 / 1493

页数：9

共 56 条

[1] SIMPLE PROCEDURE FOR EPOXIDATION OF ACID-SENSITIVE OLEFINIC COMPOUNDS WITH META-CHLOROPERBENZOIC ACID IN AN ALKALINE BIPHASIC SOLVENT SYSTEM [J].