FORMATION OF ENDOHEDRAL CARBON-CLUSTER NOBLE-GAS COMPOUNDS WITH HIGH-ENERGY BIMOLECULAR REACTIONS - C60HEN+ (N = 1,2)

被引:75
作者
WEISKE, T [1 ]
HRUSAK, J [1 ]
BOHME, DK [1 ]
SCHWARZ, H [1 ]
机构
[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY
关键词
D O I
10.1016/0009-2614(91)90209-R
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Results are reported for high-energy beam studies of the formation of adduct ions in the reactions of C60+. and C60(2+) with He and D2 in a four-sector mass spectrometer. Studies of the addition of He to C60+. at translational energies of 2, 3, 4, 5, 6 and 8 keV showed optimal adduct formation from 5 to 6 keV. The C60He2+ adduct was observed in collions between C60(2+) and He at 6 keV translational energy. No adduct formation was observed between D2 and C60+. or C60(2+) at 6 keV translational energy.
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页码:459 / 462
页数:4
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