CRITICAL-EVALUATION AND OPTIMIZATION OF THE THERMODYNAMIC PROPERTIES AND PHASE-DIAGRAMS OF THE MNO-SIO2 CAO-SIO2 SYSTEMS

被引：156

作者：

ERIKSSON, G ^{[1
]}

WU, P ^{[1
]}

BLANDER, M ^{[1
]}

PELTON, AD ^{[1
]}

机构：

[1] ARGONNE NATL LAB,DIV CHEM TECHNOL,ARGONNE,IL 60439

来源：

CANADIAN METALLURGICAL QUARTERLY | 1994年 / 33卷 / 01期

关键词：

D O I：

10.1179/000844394795539361

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

All available thermodynamic and phase diagram data have been critically assessed for all phases in the MnO-SiO2 and CaO-SiO2 systems at 1 bar pressure form 298 K to above the liquidus temperatures. All reliable thermodynamic and phase diagram data for each system have been simultaneously optimized in order to obtain one set of model equations for the Gibbs energies of all phases as functions of temperature and composition. The thermodynamic properties and phase diagrams calculated from these parameters are self-consistent and the most reliable currently available estimates of the true values. The modified quasichemical model was used to represent the Gibbs energies of the molten slag phases.

引用

页码：13 / 21

页数：9

共 67 条

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