A MONONUCLEAR MANGANESE(III) SCHIFF-BASE COMPLEX, [MN(C14H10N2O2)(C8H7O3)(CH4O)]

被引：20

作者：

DUTTA, S ^{[1
]}

MANIVANNAN, V ^{[1
]}

BABU, LG ^{[1
]}

PAL, S ^{[1
]}

机构：

[1] UNIV HYDERABAD,SCH CHEM,HYDERABAD 500134,ANDHRA PRADESH,INDIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194012151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, [2-(alpha-hydroxybenzylidenehydrazonomethyl)phenolato(2-)-N,O,O'](methanol-O)-(methyl salicylato-O,O')manganese(III), [Mn(BHS)-(MS)(CH3OH)], the manganese(III) ion is surrounded by an O5N coordination sphere. The tridentate 2-(alpha-hydroxybenzylidenehydrazonomethyl)phenolate (BHS2-) ligand (H2BHS is the benzoyl hydrazone of salicylaldehyde) binds the metal ion meridionally and the methyl salicylate (MS(-)) ligand is bidentate. The sixth position is occupied by a methanol molecule. There is a significant tetragonal elongation due to a Jahn-Teller effect.

引用

页码：813 / 815

页数：3

共 5 条

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[5]

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