MILD AND RAPID AZIDE-MEDIATED, PALLADIUM-CATALYZED CLEAVAGE OF ALLYLESTER BASED PROTECTING GROUPS

被引：27

作者：

SHAPIRO, G

BUECHLER, D

机构：

[1] Preclinical Research, Sandoz Pharma Ltd.

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(00)73515-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under palladium catalysis various allylester protecting groups are rapidly cleaved in high yield with the reagent 8:3 trimethylsilylazide/tetrabutylammonium fluoride. The efficiency of this method makes it particularly useful for solid phase deprotections.

引用

页码：5421 / 5424

页数：4

共 26 条

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