BENZENE MIGRATION AND ISOMER INTERCONVERSION IN RU5C(CO)(12)(C6H6) - COMPARISON OF SOLUTION AND ISOLATION MATRIX PHENOMENA

被引：7

作者：

BROWN, DB

DYSON, PJ

JOHNSON, BFG

PARKER, D

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] ICI PLC,WILTON MAT RES CTR,MIDDLESBROUGH TS6 8JE,CLEVELAND,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 491卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

RUTHENIUM; CARBONYL; BENZENE; PHOTOLYSIS;

D O I：

10.1016/0022-328X(94)05250-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The irradiation of Ru5C(CO)(12)(eta(6)-C6H6), in which the benzene is coordinated to a basal metal atom, embedded within a polymethylmethacrylate (PMMA) film leads to the formation of the eta(6) apical isomer. On heating, the process is reversed and conversion of the eta(6) apical into the eta(6) basal isomer is observed. Possible mechanistic pathways for these processes are discussed.

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页码：189 / 193

页数：5

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