BASE-CATALYZED HYDROGEN-TRITIUM EXCHANGE RATES OF OMEGA-TRITIUM-SUBSTITUTED PICOLINES AND METHYLQUINOLINES

被引：18

作者：

WHITE, WN

LAZDINS, D

机构：

[1] Department of Chemistry, Ohio State University, Columbus

[2] Department of Chemistry, University of Vermont, Burlington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 09期

关键词：

D O I：

10.1021/jo01261a059

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sodium methoxide catalyzed exchange rates between methanol and ω-tritium-substituted picolines and methylquinolines were determined. The relative reactivities were 2-methylquinoline > 4-picoline > 2-picoline > 3-methylquinoline > 3-picoline. These results have been interpreted by use of the qualitative resonance theory and correlated by means of LCAO-MO calculations. © 1969, American Chemical Society. All rights reserved.

引用

页码：2756 / &

共 27 条

[1] FLUOROCARBANIONS . RATES OF BASE-CATALYZED HYDROGEN-DEUTERIUM EXCHANGE ISOTOPE EFFECTS + ACIDITY OF MONOHYDROFLUOROCARBONS [J].