DIFFUSION TO FRACTAL SURFACES .4. THE CASE OF THE ROTATING-DISK ELECTRODE OF FRACTAL SURFACE

被引:22
作者
NYIKOS, L [1 ]
PAJKOSSY, T [1 ]
BOROSY, AP [1 ]
MARTEMYANOV, SA [1 ]
机构
[1] AN FRUMKIN ELECTROCHEM INST,MOSCOW 117071,USSR
关键词
hydrodynamics; Levich equation; partially active surfaces;
D O I
10.1016/0013-4686(90)85015-F
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The limiting current of a fast electrode reaction on a rotating, inactive disc with an electrochemically active fractal subset was theoretically predicted to be proportional to ωα, with ω being the rotation frequency, and the exponent α was determiend by the fractal dimension, Df, of the active area as α = (Df-1)/2. The experimental verification is presented. © 1990.
引用
收藏
页码:1423 / 1424
页数:2
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