REACTIONS OF NAPHTHALENEYTTERBIUM WITH BIS(CYCLOPENTADIENYL) COMPLEXES OF COBALT, NICKEL, CHROMIUM AND VANADIUM - X-RAY CRYSTAL-STRUCTURE OF THE TRIPLE-DECKER CPVC10H8VCP

被引：21

作者：

BOCHKAREV, MN ^{[1
]}

FEDUSHKIN, IL ^{[1
]}

SCHUMANN, H ^{[1
]}

LOEBEL, J ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,W-1000 BERLIN 12,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)83005-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Naphthaleneytterbium, C10H8Yb(THF)3 reacts with Cp2Cr, Cp2Co, Cp2Ni, and Cp2V in THF to give Cp2Yb. In the case of the reaction of C10H8Yb(THF)3 with Cp2V, vanadium-containing intermediates could be isolated. One of them, CpVC10H8VCp, has been characterized by X-ray differaction. The crystals are monoclinic, space group P2(1)/n, with a 907.0(5), b 798.8(3), c 1080.8(5) pm, beta 105.21(4)-degrees; Z = 2. The structure was refined to R = 0.0288 for 1131 observed reflections (F(o) > 4-sigma(F(o))).

引用

页码：321 / 326

页数：6

共 14 条

[1] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]
[2] SYNTHESIS AND REACTIVITY OF NAPHTHALENE COMPLEXES OF YTTERBIUM
BOCHKAREV, MN
TRIFONOV, AA
FEDOROVA, EA
EMELYANOVA, NS
BASALGINA, TA
KALININA, GS
RAZUVAEV, GA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 372 (02) : 217 - 224
[3] TRANSITION-METAL ORGANOMETALLIC COMPOUNDS .8. ARENE EXCHANGE-REACTIONS OF BIS(NAPHTHALENE)CHROMIUM
BUSH, BF
LYNCH, VM
LAGOWSKI, JJ
[J]. ORGANOMETALLICS, 1987, 6 (06) : 1267 - 1275
[4] THE 1ST TRIPLE-DECKER SANDWICH WITH A BRIDGING BENZENE-RING
DUFF, AW
JONAS, K
GODDARD, R
KRAUS, HJ
KRUGER, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (16) : 5479 - 5480
[5] EREMENKO IL, 1983, B ACAD SCI USSR CH, P2545
[6] JOHNSON CK, 1965, ORNL3794 REP
[7] JONAS K, 1986, ANGEW CHEM, V98, P904
[8] TRIS(TETRACARBONYLCOBALT)TETRAKIS(TETRAHYDROFURAN)ERBIUM
MARIANELLI, RS
DURNEY, MT
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 32 (02) : C41 - +
[9] SYNTHESIS AND MOLECULAR-STRUCTURE OF LANTHANUM TRIS[CYCLOPENTADIENYLMOLYBDENOTRICARBONYLATE] TETRAHYDROFURANATE, (THF)5LA[CPMO(CO)3]3.THF
PASYNSKII, AA
EREMENKO, IL
SULEIMANOV, GZ
NURIEV, YA
BELETSKAYA, IP
SHKLOVER, VE
STRUCHKOV, YT
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 266 (01) : 45 - 52
[10] RADKOV YF, 1988, METALLOORG KHIM, V1, P1427

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