THERMODYNAMIC PROPERTIES OF ORGANIC-COMPOUNDS .2. COMBUSTION AND SUBLIMATION ENTHALPIES OF 2,4,6-TRIMETHYLBENZONITRILE N-OXIDE

被引:9
作者
ACREE, WE
SIMIRSKY, VV
KOZYRO, AA
KRASULIN, AP
KABO, GJ
FRENKEL, ML
机构
[1] BYELORUSSIAN STATE UNIV,DEPT CHEM,MINSK 220080,BELORUSSIA,USSR
[2] TEXAS A&M UNIV SYST,THERMODYNAM RES CTR,COLLEGE STN,TX 77843
关键词
D O I
10.1021/je00005a034
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental vapor pressures and enthalpy of combustion are reported for 2,4,6-trimethylbenzonitrile N-oxide, along with the enthalpy of sublimation derived from the temperature dependence of the vapor pressure. Results of these measurements are used to compute standard enthalpies of formation in the crystalline and gaseous states, DELTA(f)H(m)-degrees-(cr) = 49.25 +/- 3.54 kJ.mol-1 and DELTA(f)H(m)-degrees-(g) = 137.0 +/- 4.0 kJ.mol-1, respectively.
引用
收藏
页码:131 / 133
页数:3
相关论文
共 20 条