AN ASYMMETRIC TOTAL SYNTHESIS OF (-)-SUPINIDINE

被引：33

作者：

TAKAHATA, H

BANBA, Y

MOMOSE, T

机构：

[1] Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University, Toyama, 930-01

来源：

TETRAHEDRON | 1991年 / 47卷 / 36期

关键词：

KATSUKI-SHARPLESS OXIDATION; AMIDOMERCURATION; ASYMMETRIC SYNTHESIS; PYRROLIZIDINE ALKALOID; (-)-SUPINIDINE;

D O I：

10.1016/S0040-4020(01)88287-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By starting from the N-alkenylurethane 4, the epoxy urethane ent-5, and the pyrrolidine ent-6 available from the Katsuki-Sharpless kinetic resolution of N-benzyloxycarbonyl-3-hydroxy-1-pentenylamine (2) has been elaborated (-)-supinidine (1).

引用

页码：7635 / 7644

页数：10

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