THE MISCIBILITY WINDOW OF POLY(METHYLMETHACRYLATE) POLY(STYRENE-CO-ACRYLONITRILE) BLENDS

被引：193

作者：

SUESS, M ^{[1
]}

KRESSLER, J ^{[1
]}

KAMMER, HW ^{[1
]}

机构：

[1] TECH UNIV DRESDEN,DEPT CHEM,MOMMSENSTR 13,DDR-8027 DRESDEN,GER DEM REP

来源：

POLYMER | 1987年 / 28卷 / 06期

关键词：

COPOLYMERS - Solubility - LIGHT - Scattering - MICROSCOPIC EXAMINATION - POLYMERS - Glass Transition;

D O I：

10.1016/0032-3861(87)90169-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The miscibility behavior of poly(methylmethacrylate)/poly(styrene-co-acrylonitrile) (PMMA/SAN) blends with changes in blend ratio and acrylonitrile content of SAN was investigated by laser light scattering. The results show a miscibility window in the temperature versus copolymer composition plane. The phase morphology was observed over the whole copolymer composition and temperature area by light microscopy. A highly interconnected two-phase structure which occurs just above the lower critical solution temperature can also be found at room temperature in a certain region just outside the composition of the miscibility window. The differential scanning calorimetry trace of miscible systems displays a broadening at high PMMA contents in the blend.

引用

页码：957 / 960

页数：4

共 11 条

[1] PARTIAL MISCIBILITY IN SYSTEM POLY(PARA-CHLOROSTYRENE-CO-ORTHO-CHLOROSTYRENE)/POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) [J].

ALEXANDROVICH, P ;

KARASZ, FE ;

MACKNIGHT, WJ .

POLYMER, 1977, 18 (10) :1022-1026

[2] THERMODYNAMIC MISCIBILITY OF POLYSTYRENE POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) BLENDS [J].

DIPAOLABARANYI, G ;

RICHER, J ;

PREST, WM .

CANADIAN JOURNAL OF CHEMISTRY, 1985, 63 (01) :223-227

[3]

Fox T. G. B., 1956, B AM PHYS SOC, V1, P123

[4] IDEAL COPOLYMERS AND THE 2ND-ORDER TRANSITIONS OF SYNTHETIC RUBBERS .1. NON-CRYSTALLINE COPOLYMERS [J].

GORDON, M ;

TAYLOR, JS .

JOURNAL OF APPLIED CHEMISTRY, 1952, 2 (09) :493-500

[5] THERMODYNAMICS OF POLYMER MISCIBILITY [J].

KAMMER, HW .

ACTA POLYMERICA, 1986, 37 (01) :1-6

[6] PHASE-BEHAVIOR OF POLY(METHYLMETHACRYLATE) AND POLY(STYRENE-CO-ACRYLONITRILE) BLENDS [J].

KRESSLER, J ;

KAMMER, HW ;

KLOSTERMANN, K .

POLYMER BULLETIN, 1986, 15 (02) :113-119

[7] COMPATIBILITY IN BLENDS OF POLY(METHYL METHACRYLATE) AND POLY(STYRENE-CO-ACRYLONITRILE) .1. PHYSICAL-PROPERTIES [J].

NAITO, K ;

JOHNSON, GE ;

ALLARA, DL ;

KWEI, TK .

MACROMOLECULES, 1978, 11 (06) :1260-1265

[8] A BINARY INTERACTION-MODEL FOR MISCIBILITY OF COPOLYMERS IN BLENDS [J].

PAUL, DR ;

BARLOW, JW .

POLYMER, 1984, 25 (04) :487-494

[9]

STEIN DJ, 1974, ANGEW MAKROMOL CHEM, V36, P89

[10] LOWER CRITICAL SOLUTION TEMPERATURE BEHAVIOR IN POLYMER BLENDS - COMPRESSIBILITY AND DIRECTIONAL-SPECIFIC INTERACTIONS [J].

TENBRINKE, G ;

KARASZ, FE .

MACROMOLECULES, 1984, 17 (04) :815-820

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