STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .20. SOLVOLYSIS OF 2-PARA-ANISYL-2-NORBORNYL AND 2-PARA-ANISYL-2-CAMPHENILYL PARA-NITROBENZOATES - EVIDENCE FOR UNIMPORTANCE OF SIGMA-PARTICIPATION AS A FACTOR IN HIGH EXO-ENDO RATE AND PRODUCT RATIOS REALIZED IN SOLVOLYSIS OF HIGHLY STABILIZED TERTIARY 2-NORBORNYL DERIVATIVES

被引：15

作者：

BROWN, HC ^{[1
]}

TAKEUCHI, K ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1977年 / 99卷 / 08期

关键词：

D O I：

10.1021/ja00450a046

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2679 / 2683

页数：5

共 27 条

[1] Bartlett P.D., 1965, NONCLASSICAL IONS
[2] BARTLETT PD, 1959, J LIEBIGS ANN CHEM, V623, P217
[3] SELECTIVE REDUCTIONS .11. REACTION OF SODIUM BOROHYDRIDE WITH ALKYL HALIDES UNDER SOLVOLYTIC CONDITIONS . BOROHYDRIDE AS A CONVENIENT TRAP FOR CARBONIUM IONS
BELL, HM
BROWN, HC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (07) : 1473 - &
[4] SOLVOLYSIS OF SUBSTITUTED 2-ARYL-EXO-NORBORNYL CHLORIDES . APPLICATION OF HAMMETT CORRELATION AS A TEST FOR SIGMA PARTICIPATION IN NORBORNYL SYSTEM
BROWN, HC
TAKEUCHI, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (22) : 5336 - +
[5] QUESTION OF SIGMA-BRIDGING IN SOLVOLYSIS OF 2-NORBORNYL DERIVATIVES
BROWN, HC
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1973, 6 (11) : 377 - 386
[6] SOLVOLYSIS OF 3-ARYL-3-NORTRICYCLYL P-NITROBENZOATES - EVIDENCE FOR MAJOR INCREASES IN ELECTRON SUPPLY BY CYCLOPROPYL GROUP WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER
BROWN, HC
PETERS, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (07) : 1927 - 1929
[7] UNUSUALLY HIGH EXO ENDO RATE RATIOS IN SOLVOLYSIS OF 2-P-ANISYLCAMPHENILYL AND RELATED COMPOUNDS - FURTHER EVIDENCE FOR STERIC EFFECTS AS A MAJOR FACTOR IN EXO ENDO RATE RATIOS OF TERTIARY NORBORNYL DERIVATIVES
BROWN, HC
TAKEUCHI, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (19) : 5268 - &
[8] EXPLORATIONS IN NONCLASSICAL ION AREA
BROWN, HC
[J]. TETRAHEDRON, 1976, 32 (02) : 179 - 204
[9] A CONVENIENT PROCEDURE FOR QUANTITATIVE CONVERSION OF REACTIVE ALCOHOLS AND OLEFINS INTO CORRESPONDING CHLORIDES
BROWN, HC
REI, MH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (04) : 1090 - &
[10] HIGH EXO - ENDO RATE RATIO AND PREDOMINANT EXO SUBSTITUTION IN SOLVOLYSIS OF 2-P-ANISYLNORBORNYL DERIVATIVES . CHARACTERISTICS OF A HIGHLY STABILIZED CLASSICAL NORBORNYL CATION
BROWN, HC
TAKEUCHI, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) : 2691 - &

← 1 2 3 →