AROMATIC SUBSTITUTION OF OLEFIN .3. REACTION OF STYRENE-PALLADIUM(2) CHLORIDE COMPLEX

被引：62

作者：

FUJIWARA, Y

MORITANI, I

MATSUDA, M

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka, Machikaneyama

来源：

TETRAHEDRON | 1968年 / 24卷 / 13期

关键词：

D O I：

10.1016/S0040-4020(01)98677-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

trans-Stilbene derivatives have been obtained from a reaction of styrene-palladium (II) complex (1) with aromatic compounds in the presence of carboxylic acids. This novel method of synthesizing stilbene derivatives by substitution of an H atom on the double bond of the styrene of complex 1 is the first case of aromatic substitution of olefins. In a typical reaction, the complex 1 with benzene and acetic acid afforded trans-stilbene in a 26 % yield and a saturated acetate (13 %), and when sodium acetate was added, the yield was surprisingly increaased. © 1968.

引用

页码：4819 / &

共 25 条

[1]

BALFE MP, 1946, J CHEM SOC, P797, DOI 10.1039/jr9460000797

[2] ON THE ADDITION OF FORMIC ACID TO DICYCLOPENTADIENE [J].