PREPARATION OF OLIGOSILANES SI8X18(X = CL, OCH3) BY PHOTOLYSIS OF SILYLMERCURY COMPOUNDS

被引：8

作者：

RAML, W

HENGGE, E

机构：

[1] Institut für Anorganische Chemie, Technische Universität Graz, Graz

来源：

MONATSHEFTE FUR CHEMIE | 1979年 / 110卷 / 05期

关键词：

Oligosilanes; Photolysis; Silanes; Silylmercury compounds;

D O I：

10.1007/BF00910974

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of SiSi-bonds by a photochemical reaction of silylmercury compounds is described. The silylmercury compounds [(X3Si)3Si]2Hg (X=Cl, OCH3) were synthesized via the Vyazankin Hydrid method with (X3Si)3SiH and Bis(t-butyl)mercury. By UV-irradiation of these products in hexane as a solvent, the oligosilanes [(X3Si)3Si]2 are formed in good yields. All these compounds are charactericed by spectroscopical methods. © 1979 Springer-Verlag.

引用

页码：1257 / 1261

页数：5

共 10 条

[1] SYNTHESIS OF NOVEL CHLOROSILYL AND CHLOROGERMYL MERCURIALS WITH SOME OF THEIR CHEMICAL REACTIONS [J].