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MOLECULAR RECOGNITION OF GEOMETRICAL-ISOMERS IN MONTMORILLONITE

被引：7
作者：
CHOUDARY, BM
BHARATHI, P
RAO, KK
SARMA, MR
KANTAM, ML
机构：
[1] Homogeneous Catalysis Discipline, Indian Institute of Chemical Technology, Hyderabad
来源：
CATALYSIS LETTERS | 1993年 / 19卷 / 04期
关键词：
MOLECULAR RECOGNITION; MONTMORILLONITE CATALYST; MOLECULAR RECOGNITION BY CLAY CATALYSTS;
D O I：
10.1007/BF00767070
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
cis-alkenes are hydrogenated preferentially followed by trans-alkenes sequentially from the mixture of geometrical isomers by the montmorillonitebipyridylpalladium(II) acetate catalyst. Such molecular recognition in montmorillonite is unusual and remarkable, and forms an advanced model to enzymes.
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页码：293 / 298
页数：6
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