ELECTROSTATIC CATALYSIS OF THE HYDROLYSIS OF A PHOSPHATE DIESTER IN WATER

被引:12
作者
DALBY, KN [1 ]
HOLLFELDER, F [1 ]
KIRBY, AJ [1 ]
机构
[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND
关键词
D O I
10.1039/c39920001770
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The efficiency of general acid catalysis by protonated amines of the hydrolysis of a phosphate diester with a neighbouring nucleophilic OH group depends less on the pK(a) of the acid than on the proximity of a second positive charge.
引用
收藏
页码:1770 / 1771
页数:2
相关论文
共 5 条
  • [1] CHANDLER AJ, 1992, J CHEM SOC CHEM COMM, P1767
  • [2] DALBY KN, 1992, THESIS CAMBRIDGE
  • [3] DALBY KN, UNPUB J CHEM SOC P2
  • [4] FERSHT AR, 1985, ENZYME STRUCTURE MEC, P428
  • [5] JENCKS WP, 1969, CATALYSIS CHEM ENZYM, P173