3RD-ORDER NONLINEAR-OPTICAL PROPERTIES OF ONE-DIMENSIONAL METAL-COMPLEXES

被引：41

作者：

KAMATA, T

FUKAYA, T

MIZUNO, M

MATSUDA, H

MIZUKAMI, F

机构：

[1] National Institute of Materials and Chemicals Research, Tsukuba, Ibaraki

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 221卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(94)00268-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The third-order non-linear optical properties of evaporated thin films of d8 transition metal complexes with dionedioxime have been estimated by third harmonic generation. They formed one-dimensional structures and showed large optical non-linearities. Resonance effects were observed for respective metal complexes. The maximum chi(3) value of 5.6 x 10(-11) esu was obtained at the near three-photon resonance wavelength for the platinum complex. The delocalized electrons in linear metal chains may be essential for exhibiting large non-linear optical effects.

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页码：194 / 198

页数：5

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